To learn Jj Cale - Rio chords, anchor your practice on these foundational sequence of chords - G#, C#m, G#, G#m, F#m, C#m, F#, C#m, F#m, C#m and G#m. I suggest starting at a calm pace of 49 BPM, and as you gain confidence, approach the song's BPM of 99. Given the song's key of C# Minor, adjust the capo to align with your vocal range and chord preference.
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Facts about this song
This song was featured on the To Tulsa and Back album.