To learn Divinyls - Punxsie chords, your first step should be understanding these chords - Em, D, A, G, Em, A, Bm, Em, D and E in sequence. A strategic approach would be to train at 66 BPM initially, and then accelerate to the song's tempo of 133. With D Major as the song's key, tweak the capo to cater to your vocal pitch and chord likes.